When Sony Pictures and Marvel Studios made the deal to bring Spider-Man to the MCU, it was stated that they wouldn’t be reusing any of the villains that were previously seen on the big screen. Spider-Man: Homecoming will introduce Vulture to the casual Spider-Man fans. The role will be played by Batman himself, Michael Keaton.
However, it looks like another classic villain will be coming into the fold, one created by the original team of Steve Ditko and Marvel godfather Stan Lee in Amazing Spider-Man #10.
Prometheus actor Logan Marshall-Green will be playing a character named Jackson Brice aka Montana. Montana appeared in the early Spidey issues as a member of the Enforcers.